Chemistry · Class 12 · Principles Related to Practical Chemistry

Principles Related to Practical Chemistry for JEE

Everything you need for this topic on one page: the ideas, the formulas, the traps, and free lectures that explain it well.

Last updated: 26 October 2026

Direct answer

Detection of functional groups, salt analysis (cations and anions), titrations and preparation of standard compounds listed in the syllabus.

Detection of functional groups, salt analysis (cations and anions), titrations and preparation of standard compounds listed in the syllabus.

Key ideas

Principles Related to Practical Chemistry: what you must understand

  • Functional group tests: Tollens', Fehling's, FeCl₃, iodoform, carbylamine
  • Salt analysis groups depend on reagents and solubility
  • Indicators: phenolphthalein for strong base, methyl orange for strong acid
  • Mohr's salt and oxalic acid titrations with KMnO₄
Formula sheet

Must-know formulas for Principles Related to Practical Chemistry

  • Titration: N₁V₁ = N₂V₂
  • Group II cations precipitate with H₂S in acid
  • Carbylamine test: 1° amine + CHCl₃/KOH → isocyanide smell
  • Brown ring test for nitrate
Print

One-page formula sheet

Printable Principles Related to Practical Chemistry formula sheet: formulas, key ideas and traps on one page. Save it as a PDF for offline revision.

Avoid

Common mistakes students make

  • Mixing group reagents
  • Wrong indicator choice
  • Forgetting the carbylamine test is only for 1° amines
For the exam

How this topic is asked in JEE

Appears regularly; quick marks. An official unit with direct, memory-based questions.

NCERT map

Where Principles Related to Practical Chemistry is in NCERT

Chapter names follow the current rationalised NCERT textbooks. Read these sections before solving PYQs.

ClassBookChapterSections JEE asks from
Class 11ChemistryThe s-Block ElementsAnomalous Properties of Lithium; General Characteristics of the Compounds of the Alkali Metals; Sodium Chloride; Sodium Hydroxide
Class 12Chemistry Part IThe d- and f-Block ElementsGeneral Properties of the Transition Elements; Some Important Compounds of Transition Elements; Potassium Dichromate; Potassium Permanganate
Class 12Chemistry Part IIAldehydes, Ketones and Carboxylic AcidsChemical Reactions of Aldehydes and Ketones; Tests to Distinguish Aldehydes from Ketones
Class 11ChemistryOrganic Chemistry: Some Basic Principles and TechniquesDetection of Elements; Qualitative Analysis of Organic Compounds
JEE Advanced level

A JEE Advanced-level example on Principles Related to Practical Chemistry

Question. A hydrated salt (A) of a divalent metal shows the following: (i) Violet color in borax bead test in both oxidizing and reducing flames. (ii) White precipitate with BaCl₂ solution that is insoluble in concentrated HCl. (iii) On strong heating, it decomposes to give a residue (B) and gaseous oxides of sulfur. (iv) 2.77 g of (A) on complete thermal decomposition gives 0.71 g of residue (B). Identify salt (A) and find the number of water molecules of crystallization.

Show solution
  1. Violet borax bead in both flames indicates Mn²⁺ cation
  2. White ppt with BaCl₂ insoluble in conc. HCl confirms SO₄²⁻ anion, so salt is MnSO₄·xH₂O
  3. Thermal decomposition: MnSO₄·xH₂O → MnO + SO₃ + xH₂O, residue (B) is MnO (molar mass = 71 g/mol)
  4. Moles of MnO = 0.71/71 = 0.01 mol, so moles of salt = 0.01 mol
  5. Molar mass of salt = 2.77/0.01 = 277 g/mol. Since MnSO₄ = 151 g/mol, mass of water = 277 − 151 = 126 g/mol
  6. Number of water molecules x = 126/18 = 7

Answer: Salt (A) is MnSO₄·7H₂O (manganese sulfate heptahydrate) with 7 water molecules of crystallization

This example was solved twice independently and both solutions agree.

Free lectures

Best free lectures for Principles Related to Practical Chemistry

Full-chapter free lectures picked from YouTube search results by views, from established JEE channels (mostly in Hinglish). Use the subtopic list to jump straight to the part you need (timestamps come from each video's own chapter list). Watch one, then solve PYQs the same day.

FAQs

Frequently asked questions

Is Principles Related to Practical Chemistry important for JEE Main 2027?

Appears regularly; quick marks. It is part of the official 'Principles Related to Practical Chemistry' unit in the JEE Main 2027 syllabus.

What are the most important formulas in Principles Related to Practical Chemistry?

Titration: N₁V₁ = N₂V₂; Group II cations precipitate with H₂S in acid; Carbylamine test: 1° amine + CHCl₃/KOH → isocyanide smell.

How should I study Principles Related to Practical Chemistry for JEE?

Understand the key ideas from NCERT or one full lecture, learn the formula sheet, then solve 25–30 past JEE questions on the topic. An official unit with direct, memory-based questions.

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