⚖️ Chemical Equilibrium
Physical ChemistryCommon questions
What is chemical equilibrium?
The state where forward and reverse reaction rates are equal, so concentrations remain constant. Equilibrium is dynamic — reactions continue but net change is zero.
What is Le Chatelier's principle?
If a system at equilibrium is disturbed (concentration, pressure, temperature change), it shifts to counteract the disturbance and restore equilibrium.
How does temperature affect equilibrium?
For exothermic reactions: increasing T shifts equilibrium left (K decreases). For endothermic: increasing T shifts right (K increases). Temperature actually changes K.
What is the difference between Kp and Kc?
Kp uses partial pressures, Kc uses molar concentrations. Relation: Kp = Kc(RT)^Δn where Δn = moles of gaseous products − moles of gaseous reactants.
How many JEE questions come from equilibrium?
2-3 questions in JEE Main typically. Calculation of K, effect of perturbations, relation between Kp and Kc, and degree of dissociation are the most common types.